EAPCET Chemistry · Intermediate first year
Hydrogen and its Compounds
This chapter covers hydrogen’s isotopes, its preparation and properties, hydrides, water and its hardness, and hydrogen peroxide.
- Subject
- Chemistry
- Taught in
- Intermediate first year
- Chemistry in the paper
- 40 of 160 questions
Key formulas and results
- Isotopes: protium, deuterium and tritium (radioactive)
- Temporary hardness (bicarbonates) is removed by boiling; permanent hardness (chlorides, sulphates) is not
- Hydrogen peroxide acts as both an oxidising and a reducing agent
- Heavy water (D₂O) is used as a moderator in nuclear reactors
- Hydrides are classified as ionic, covalent or metallic
What this chapter covers
- Position and isotopes of hydrogen
- Preparation and properties
- Hydrides
- Water and hardness of water
- Heavy water
- Hydrogen peroxide
How it is usually asked
- Properties and structure of H₂O₂
- Types of hardness and their removal
- Classifying hydrides
Understanding Hydrogen and its Compounds
Hydrogen has the configuration 1s¹, so it resembles the alkali metals (it loses one electron) and the halogens (it gains one electron to reach a noble-gas configuration), which is why its position in the periodic table is debated. It has three isotopes — protium, deuterium and radioactive tritium — that differ only in neutrons, so they have the same chemistry but different rates of reaction. Hydrides are ionic with s-block metals, covalent with p-block elements, and metallic (often non-stoichiometric) with d- and f-block metals.
Hardness of water comes from dissolved Ca²⁺ and Mg²⁺. Temporary hardness, from bicarbonates, is removed by boiling or by Clark’s method (adding slaked lime), which precipitates CaCO₃ and Mg(OH)₂. Permanent hardness, from chlorides and sulphates, needs washing soda, Calgon (sodium hexametaphosphate) or ion-exchange resins. Heavy water, D₂O, is used as a moderator in nuclear reactors and to study reaction mechanisms.
Hydrogen peroxide has a non-planar, open-book structure and can act as both an oxidising and a reducing agent, because oxygen in it is in the −1 state, between 0 and −2. Its concentration is often expressed as volume strength: “10 volume” H₂O₂ means 1 L of solution gives 10 L of O₂ at STP on decomposition. EAPCET typically tests volume strength, hardness removal and the classification of hydrides.
Worked example
EAPCET-style question
What is the molarity of a “10 volume” hydrogen peroxide solution? (Take the molar volume at STP as 22.4 L.)
- (1)0.45 M
- (2)0.89 M
- (3)1.79 M
- (4)8.9 M
Solution
- Decomposition: , so 2 mol give 1 mol (22.4 L) at STP.
- 10 volume means 1 L of solution releases 10 L of : moles of .
- Moles of in 1 L.
- Molarity ; equivalently, volume strength molarity.
- 0.45 M is the moles of O₂, and 1.79 is the normality (n-factor 2), not the molarity.
Answer: 0.89 M
Common mistakes to avoid
- Writing Mg(HCO₃)₂ → MgCO₃ on boiling — magnesium precipitates as Mg(OH)₂ because it is less soluble than MgCO₃.
- Assuming boiling removes all hardness — chlorides and sulphates (permanent hardness) stay dissolved and need Calgon, washing soda or ion exchange.
- Drawing H₂O₂ as planar — it has an open-book, non-planar structure.
- Confusing normality with molarity in volume-strength questions — volume strength = 11.2 × M = 5.6 × N.
How to prepare it
A compact, factual chapter — reliable marks for one focused revision.
Once the formulas feel familiar, test them the way the exam does: practise Hydrogen and its Compounds questions chapter-wise, then attempt a full previous year paper to see whether it holds up under a 3-hour timer.
Related Chemistry chapters
- Chemical Equilibrium and Acids-BasesIntermediate first year
- The s-Block Elements (Alkali and Alkaline Earth Metals)Intermediate first year
- p- Block Elements Group 13 (Boron Family)Intermediate first year
See every chapter in the EAPCET Chemistry syllabus.
Practise Hydrogen and its Compounds chapter-wise
Chapter-wise quizzes show exactly which topics in this chapter you still get wrong — before a full paper does.
Frequently asked questions
- Is Hydrogen and its Compounds part of the EAPCET Chemistry syllabus?
- Yes. Hydrogen and its Compounds is taught in Intermediate first year Chemistry, and the EAPCET Engineering syllabus is based on the Intermediate first- and second-year syllabus. Check the official notification each year for any changes.
- How should I prepare Hydrogen and its Compounds for EAPCET?
- A compact, factual chapter — reliable marks for one focused revision.
- How many Chemistry questions are there in EAPCET?
- 40 of the 160 questions in the Engineering paper are Chemistry, spread across 24 chapters.
- What mistakes do students make in Hydrogen and its Compounds?
- Writing Mg(HCO₃)₂ → MgCO₃ on boiling — magnesium precipitates as Mg(OH)₂ because it is less soluble than MgCO₃. Assuming boiling removes all hardness — chlorides and sulphates (permanent hardness) stay dissolved and need Calgon, washing soda or ion exchange. Drawing H₂O₂ as planar — it has an open-book, non-planar structure. Confusing normality with molarity in volume-strength questions — volume strength = 11.2 × M = 5.6 × N.